Indexing Metadata
TiO2 Supported Pt Based Bimetallic Nanocatalysts for Selective Hydrogenation of Citral |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | TiO2 Supported Pt Based Bimetallic Nanocatalysts for Selective Hydrogenation of Citral |
| 2 | Creator | Author's name, affiliation, country | S. A. ANANTHAN, R. SURESH, K. GIRIBABU,
R. MANIGANDAN and V. NARAYANAN
Department of Inorganic Chemistry, School of Chemical Sciences, University of Madras,
Guindy Campus, Chennai-600 025, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Bimetallic nanocatalysts, TiO2 supported, SMSI effect, Thermal reduction, Citral hydrogenation, Unsaturated alcohols |
| 4 | Description | Abstract | TiO2 supported Pt based bimetallic nanocatalysts were prepared by impregnation method and reduced at two different temperatures, 375 °C and 575 °C for the selective hydrogenation of citral to the corresponding unsaturated alcohols namely; geraniol (GOL) and nerol (NOL). The catalysts were characterized by BET surface area measurement, FT-IR, SEM, EDAX, TEM, XRD and XPS. The prepared nanocatalysts are uniformly dispersed with an average particles size 50-100 nm and zero valence metallic state. The SMSI (Strong Meal-Support Interaction) effect shows that the catalysts reduced at higher temperature leads to an increase in selectivity toward unsaturated alcohols (GOL & NOL) for Pt-Ru/TiO2 compared to Pt-Pd/TiO2 and Pt-Au/TiO2 nanocatalysts. In addition a second metal (Ru) also leads to an increase of the GOL & NOL selectivity during the citral hydrogenation. The generated partially oxidized second metal species due to the difference in electronegativity, strongly binds the C=O group and also paves the way for the selective activation of the C=O bond. Metal support interaction and promoter active metal interaction increased the unsaturated alcohol formation. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 2 , Number (S1), (2013) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
|
