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Application of Nanoscale Zero-Valent Iron in the Remediation of DDT from Contaminated Water

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1TitleTitle of DocumentApplication of Nanoscale Zero-Valent Iron in the Remediation of DDT from Contaminated Water
2CreatorAuthor's name, affiliation, country T. POURSABERIa, E. KONOZb*, A. H. MOHSEN SARRAFIb, M. HASSANISADIa and F. HAJIFATHLIb
aResearch Institute of Petroleum Industry, Tehran, Iran
bDepartment of Chemistry, Islamic Azad University, Central Tehran branch, Tehran, Iran
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Nano zero-valent iron, DDT, Remediation, Water
4DescriptionAbstract Nanoscale zero-valent iron (NZVI) was synthesized and tested to remediate DDT (Dichlorodiphenyltrichloroethane) from the contaminated water. The influence of experimental variables such as reaction time, NZVI particle dosage and pH were studied. Mixing an aqueous solution of 3 mg L-1 DDT with 30 mg L-1 Fe0 resulted in 99.2% loss of DDT within 4 h. Solvent extraction of the Fe0 revealed that DDT removal was not through adsorption and as Fe0 treatment of DDT lead to new chromatographic peaks (degradation products) in GC analysis and chloride release, removal occurred through dechlorination. GC/MS analysis confirmed the formation of completely dechlorinated hydrocarbon skeleton of DDT namely, diphenylethane (DPE), as the end product in this treatment; thereby implying the removal of all five chlorine atoms (three alkyl and two aryl) of DDT.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  1 , Number  (3), (2012)
12LanuguageEnglish=en en
13RelationSupp.files
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Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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