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Preparation and Characterization of the Adducts of
Bis(N,N-diethyldithiocarbamato)oxovanadium(IV) and Copper(II) with n-Propylamine and Isopropylamine |
DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
1 | Title | Title of Document | Preparation and Characterization of the Adducts of
Bis(N,N-diethyldithiocarbamato)oxovanadium(IV) and Copper(II) with n-Propylamine and Isopropylamine |
2 | Creator | Author's name, affiliation, country | MOUSAMI SHARMA, ANJU SHARMA and RENU SACHAR Department of Chemistry, University of Jammu, Babasaheb Ambedkar Road,
Jammu-180006, India |
3 | Subject | Dicipline(s) | Chemical Science |
3 | Subject | Keywords | Diethyldithiocarbamate, n-Propylamine, Isopropylamine, Diethylamine, Sclerotium rolfsii |
4 | Description | Abstract | Two new 1:1 adducts of VO(dedtc)2, two 1:1 and two 1:2 adducts of Cu(dedtc)2 (where dedtc = diethyldithiocarbamate) with n-propylamine and isopropylamine have been prepared. The resulting complexes have been characterized by elemental analysis, molar conductance, magnetic susceptibility, IR and UV-Vis spectral and TGA/DTA techniques. Analytical data reveals that VO(IV) complex forms only 1:1 adducts with the formula [VO(dedtc)2L] while Cu(II) complex forms both 1:1 and 1:2 adducts with 1:1 adducts having general formula Cu(dedtc)2. L and 1:2 adducts having general formula Cu(dedtc)2.L2 (L = n-propylamine and isopropylamine). Antifungal activity of some complexes has been carried out against the fungal strain Sclerotium rolfsii. Electronic and magnetic measurements indicate a square pyramidal geometry for the 1:1 adducts of Cu(II) complex and an octahedral geometry for the 1:1 adducts of VO(IV) complex and for the 1:2 adducts of Cu(II) complex. |
5 | Publishers | Organizing agency, location | WWW Publications, India |
6 | Contributor | Sponsor(s) | - |
7 | Date | Date (YYYY-MM-DD) | - |
8 | Type | Status & genre | Peer-reviewed Article |
8 | Type | Type | |
9 | Formate | File Formate | PDF |
10 | Identifier | Uniform Resource Identifier | Click Here |
10 | Identifier | Digital Object Identifier | |
11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 2 , Number (2), (2013) |
12 | Lanuguage | English=en | en |
13 | Relation | Supp.files | |
14 | Coverage | | - |
15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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