DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
1 | Title | Title of Document | Electrochemical Study of Complexes of Tl(I) with
Asparagine at DME in Non-Aqueous Medium |
2 | Creator | Author's name, affiliation, country | MADHU MOYAL and O.D. GUPTA Department of Chemistry, University of Rajasthan, Jaipur- 302004, India |
3 | Subject | Dicipline(s) | Chemical Science |
3 | Subject | Keywords | DC Polarogrpahy, Formation constants, Tl(I), Asparagine, DMF, Ethanol |
4 | Description | Abstract | The polarographic measurements have been used to determine the overall formation constants of simple complexes of Tl(I) with asparagine. The reduction of complexes is found to be involving one electron. DeFord and Hume’s treatment suggests that aspargine forms 1:1 and 1:2 complexes in non-aqueous medium (20% and 40% v/v ethanol-water mixtures and 20% and 40% v/v DMF-water mixtures) at 298 K and 308 K. The overall formation constants log ß1 and log ß2 have been calculated for Tl(I)-Asparagine system. The thermodynamic functions ΔG°, ΔH° and ΔS° have been determined for both the complexes at 298 K in 20% and 40% ethanol-water mixtures and 20% and 40% DMF-water mixtures. |
5 | Publishers | Organizing agency, location | WWW Publications, India |
6 | Contributor | Sponsor(s) | - |
7 | Date | Date (YYYY-MM-DD) | - |
8 | Type | Status & genre | Peer-reviewed Article |
8 | Type | Type | |
9 | Formate | File Formate | PDF |
10 | Identifier | Uniform Resource Identifier | Click Here |
10 | Identifier | Digital Object Identifier | |
11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 2 , Number (1), (2013) |
12 | Lanuguage | English=en | en |
13 | Relation | Supp.files | |
14 | Coverage | | - |
15 | Copyright | Copyright and permissions | |