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Metal Ion Catalyzed Oxidation of L-Lysine by Alkaline Permanganate Ion-A Kinetic and Mechanistic Approach

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1TitleTitle of DocumentMetal Ion Catalyzed Oxidation of L-Lysine by Alkaline Permanganate Ion-A Kinetic and Mechanistic Approach
2CreatorAuthor's name, affiliation, country B. MOHANTY, J. BEHERA, S. ACHARYA, P. MOHANTY and A.K. PATNAIK
P.G.Department of Chemistry, Utkal University, Bhubaneswar-751004, Odisha, India
I.M.M.T, Bhubaneswar, Orissa, India
P.G.Department of Chemistry, Ravenshaw University, Cuttack, Odisha, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Kinetics, Metal ion, Catalysed oxidation, L-lysine, Spectrophotometrically, Activation parameter
4DescriptionAbstract The kinetics of copper(II), nickel(II) and zinc(II) catalyzed oxidation of L-lysine by potassium permanganate in alkaline medium were studied spectrophotometrically. The reaction is first order with respect to [oxidant], [substrate] and [alkali] respectively. The results suggests the formation of a complex between the amino acid and lysine and the hydroxylated species of copper(II), nickel(II) and zinc(II). The reaction constants involved in the mechanism and the activation parameters have been calculated. The reactivity order of the catalyst is Cu(II) > Ni(II) > Zn(II).
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2013.282
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (1), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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