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Electrochemical Reactions at Sacrificial Electrode: Direct Electrochemical Synthesis of Cadmium(II) Thiolates and their Coordination Compounds

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1TitleTitle of DocumentElectrochemical Reactions at Sacrificial Electrode: Direct Electrochemical Synthesis of Cadmium(II) Thiolates and their Coordination Compounds
2CreatorAuthor's name, affiliation, country BALJIT SINGH, KANCHAN BALA, GURPREET KAUR and SIMRAT SINGH
Department of Chemistry, Punjabi University, Patiala-147002, Punjab, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Electrochemical reactions, Sacrificial electrode, Cadmium(II) thiolates
4DescriptionAbstract The electrochemical synthesis of sulphur containing compounds derived from thiols (Ethanethiol, 2-propanethiol, 1-butanethiol, 2-methyl-2-propanethiol, 1-pentanethiol and thiophenol) at sacrificial cadmium anode and inert platinum cathode is reported. Adducts of these compounds with 1,10 phenanthroline and 2,2-bipyridyl (L) have also been obtained by addition of these coligands to the electrolysis phase. These compounds have been characterized by microanalysis, physical measurements and IR spectral studies. General formula conforms to    Cd(SR)2 and Cd(SR)2.L. Current efficiencies of all these reactions are quite high.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2013.290
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (1), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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