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Electrical Impedance and Structural Studies of Fast-Ion Conducting System (SbI3)x- (Ag2WO4)1-x (0.1 ≤ x ≤ 0.5)

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1TitleTitle of DocumentElectrical Impedance and Structural Studies of Fast-Ion Conducting System (SbI3)x- (Ag2WO4)1-x (0.1 ≤ x ≤ 0.5)
2CreatorAuthor's name, affiliation, country S. AUSTIN SUTHANTHIRARAJ and S. SAROJINI
Department of Energy, University of Madras, Guindy Campus, Chennai-600 025, India
PG and Research Department of Physics, Queen Mary’s College, Chennai-600 004, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Complex impedance, Electrical conductivity, XRD, Superionic solids, Transport properties
4DescriptionAbstract This paper deals with the preparation and characterization of silver ion conducting system composed of (SbI3)x- (Ag2WO4)1-x to identify the superionic conducting compositions. Powder samples of various compositions containing x=0.1, 0.2, 0.3, 0.4 and 0.5 mole fraction respectively were synthesized by rapid melt-quenching method. These samples were characterized using x-ray diffraction (XRD) and differential scanning calorimetry (DSC) studies. Their electrical transport properties were studied using complex impedance analysis. The realization of the typical ionic conductivity values of 5.7×10-2, 5.5×10-3 and 1.8×10-3 S cm-1 for the compositions (SbI3)0.4 – (AgW04)0.6, (SbI3)0.2 – (Ag2W04)0.8 and (SbI3)0.3 – (Ag2W04)0.7 respectively at room temperature has been discussed in terms of the observed characteristics.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2013.305
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (1), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
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