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Synthesis and Spectroscopic Characterization of Blue Copper Model Schiff Base Complexes

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1TitleTitle of DocumentSynthesis and Spectroscopic Characterization of Blue Copper Model Schiff Base Complexes
2CreatorAuthor's name, affiliation, country A. KULANDAISAMY, T. KAVITHA, S. ANGAIARKANNI and P. THILLAIARASU
Department of Chemistry, Raja Doraisingam Government Arts College, Sivagangai -630561, India
Department of Chemistry, Sri Ramasamy Naidu Memorial College, Sattur - 626203, India
Department of Chemistry, Alagappa Government Arts College, Karaikudi -630003, India
Department of Chemistry, Kalasalingam University, Krishnankoil - 626190, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Blue copper protein, Synthesis, Schiff base complexes, Spectroscopic characterization
4DescriptionAbstract Low molecular weight, low symmetric complexes simulating blue copper protein have been prepared by a reaction between salicylidene-4-aminoantipyrinyl-2-imino pyridine and metal salts. The complexes were characterized by elemental analysis, molar conductivity, magnetic susceptibility data, IR, 1H NMR, UV-Vis, FAB-Mass and EPR spectral studies. The physicochemical studies and spectral data indicate that the ligand acts as a monovalent tridentate chelating agent. All the complexes have the general composition MLX (M= Cu(II), Ni(II), Co(II) and Zn(II); L = Schiff base and X = Cl/Br/OAc). The UV-Vis., cyclic voltammetry and EPR spectral data of the complexes suggested that [CuLCl] complex is mimic the blue copper model type 1 proteins. But other two copper complexes are square planar geometry around the central metal ion and they were non-model complexes.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2013.31
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (S1), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
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