Indexing Metadata
Synthesis and Spectroscopic Characterization of
Blue Copper Model Schiff Base Complexes |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Synthesis and Spectroscopic Characterization of
Blue Copper Model Schiff Base Complexes |
| 2 | Creator | Author's name, affiliation, country | A. KULANDAISAMY, T. KAVITHA, S. ANGAIARKANNI and P. THILLAIARASU
Department of Chemistry, Raja Doraisingam Government Arts College,
Sivagangai -630561, India
Department of Chemistry, Sri Ramasamy Naidu Memorial College, Sattur - 626203, India
Department of Chemistry, Alagappa Government Arts College, Karaikudi -630003, India
Department of Chemistry, Kalasalingam University, Krishnankoil - 626190, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Blue copper protein, Synthesis, Schiff base complexes, Spectroscopic characterization |
| 4 | Description | Abstract | Low molecular weight, low symmetric complexes simulating blue copper protein have been prepared by a reaction between salicylidene-4-aminoantipyrinyl-2-imino pyridine and metal salts. The complexes were characterized by elemental analysis, molar conductivity, magnetic susceptibility data, IR, 1H NMR, UV-Vis, FAB-Mass and EPR spectral studies. The physicochemical studies and spectral data indicate that the ligand acts as a monovalent tridentate chelating agent. All the complexes have the general composition MLX (M= Cu(II), Ni(II), Co(II) and Zn(II); L = Schiff base and X = Cl/Br/OAc). The UV-Vis., cyclic voltammetry and EPR spectral data of the complexes suggested that [CuLCl] complex is mimic the blue copper model type 1 proteins. But other two copper complexes are square planar geometry around the central metal ion and they were non-model complexes. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 2 , Number (S1), (2013) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
|
