Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
Home | Table of Contents | Submit an article | Subscribe | Login | Register

Indexing Metadata

Synthesis, Characterization, Electrochemical and Antimicrobial Activity of Macrocyclic Binuclear Cu(II), Ni(II) and VO(II) Schiff Base Complexes

DUBLINCOREMETADATA ITEM METADATA FOR THIS DOCUMENT
1TitleTitle of DocumentSynthesis, Characterization, Electrochemical and Antimicrobial Activity of Macrocyclic Binuclear Cu(II), Ni(II) and VO(II) Schiff Base Complexes
2CreatorAuthor's name, affiliation, country D. SANDHANAMALAR, S. VEDANAYAKI and R. RAJAVEL
Department of Chemistry, Periyar University, Salem-636 011, India
Department of Chemistry, Kandaswami Kandarís College, P. Velur, Namakkal-638182, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Tetradentate macrocyclic Schiff base, EPR, Cyclic voltametry, Square-pyramidal, Aspergillus fumigates
4DescriptionAbstract A template condensation of 3,3í- diaminobenzidine with benzil and dimethyl ortho- phenylenediamine in the presence of Cu(II), Ni(II) and VO(II) resulted in the formation of tetradentate macrocyclic Schiff base binuclear complexes of the type [M2 L.X] and [M2 L]. X2 (where, X= 2ClO4-, CH3COO- and 2SO4-). Structural characterization of the complexes were achieved by several physicochemical methods, namely elemental analysis, electronic spectra, infrared, EPR, cyclic voltammetry, molar conductivity and magnetic susceptibility measurements. A square planar binuclear structure was proposed for the perchlorate anions in Cu(II) and Ni(II) complexes. Whereas the square pyramidal environment around the VO(II) center. The Schiff base complexes were investigated for antibacterial and antifungal properties of gram-positive bacteria (taphylococcus auerus), gram-negative bacteria (pseudomonas fluorescens) and fungi (Aspergillus fumigates) were used in this study to assess their antimicrobial properties. The results showed that this skeletal framework exhibit marked potency as antimicrobial agents.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2013.332
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (2), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
Home | Table of Contents | Submit an article | Subscribe | Login | Register