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Synthesis, Characterization and Biological Studies of Some Thiocyanato-bridged Bimetallic Complexes Containing Co(II), Cd(II), Hg(II) and N, Nl-Bis(benzylidene)-1,2-phenylene-diamine Schiff Base

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1TitleTitle of DocumentSynthesis, Characterization and Biological Studies of Some Thiocyanato-bridged Bimetallic Complexes Containing Co(II), Cd(II), Hg(II) and N, Nl-Bis(benzylidene)-1,2-phenylene-diamine Schiff Base
2CreatorAuthor's name, affiliation, country N. UPADHAYAY
Department of Chemistry, Pt. SNS Govt. PG College, Shahdol-(M P), India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Bimetallic, Thiocyanato, Schiff base, Synthesis
4DescriptionAbstract The coordination chemistry of transition metal complexes has been progressing at a tremendous pace. These complexes were finding use in the field of homogeneous catalysis, analytical chemistry and biological system. The presence of thiocyanto group in mixed ligand coordinated complexes of transition metal was reported to have an ability to influence the biochemical behaviour of the complexes. Complexes of MM’(SCN)4 (M = Co2+ ; M’ = Cd2+, Hg2+) with N, N'–bis (benzylidene) -1, 2, phenylenediamine Schiff base of molecular formula [MM'(SCN)4(BENDAMB) (1, 2)] have been synthesized and characterized by elemental analyses, molar conductance magnetic moment, IR, electronic and 1H NMR spectral studies. The softness parameter Ten of complexes have also been calculated to derive the binding side of the thiocyanate ligand. The insecticidal activity against Red cotton bug (Dysdercus koenigii) and antifungal activity against A.Flavus and F.Solani of complexes also been investigated and was compared with solvent and Schiff base.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2013.391
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (2), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
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