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Coordination Aspects of Newly Synthesised Complexes of Some Divalent Transition Metals with 2,4-Dichlorophenoxy Acetate and Hydrazine

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1TitleTitle of DocumentCoordination Aspects of Newly Synthesised Complexes of Some Divalent Transition Metals with 2,4-Dichlorophenoxy Acetate and Hydrazine
2CreatorAuthor's name, affiliation, country R. MANIMEKALAI*, K. KALPANADEVI and C. R. SINDUJA
Department of Chemistry, Kongunadu Arts and Science College, Coimbatore, Tamilnadu- 641029, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Hydrazine, 2,4 Dichlorophenoxy acetate, TG-DTA, Divalent transition metals
4DescriptionAbstract A new series of hydrazine complexes of 3d transition metal 2,4 dichlorophenoxy acetates of the formula M(2,4 di-Cl PhOAc) 2(N2H4)2,where M = Mn, Co, Ni or Cd have been prepared and studied. The compositions of the complexes have been determined by chemical analyses. Infrared spectral data indicate the bidentate bridging by hydrazine molecules and unidentate coordination by carboxylate ions. Thermogravimetry and differential thermal analyses in air have been used to study the thermal behaviour of the complexes. The simultaneous TG-DTA traces of all the complexes show multi-step degradation and the final products are found to be the respective metals.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (3), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
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15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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