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Electrochemical Reduction Bahaviour of Vinclozolin Fungicide at Platinum Electrode

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1TitleTitle of DocumentElectrochemical Reduction Bahaviour of Vinclozolin Fungicide at Platinum Electrode
2CreatorAuthor's name, affiliation, country N. Y. SREEDHAR*, CH. SWARUPA, M. SIVAPRASAD, M. SEENU NAIK and M. DHANANJAYULU
Electroanalytical Lab, Department of Chemistry, Sri Venkateswara University, Tirupati-517502, Andhra Pradesh, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Vinclozolin, Cyclic voltammetry, LSV, Platinum electrode, Reduction, LOD
4DescriptionAbstract The electrochemical behavior of vinclozolin [3-(3,5-dichlorophenyl)-5-methyl-5-vinyl-1,3 oxazolidine-2,4-dion] in dimethylsulfoxide was performed by cyclic voltammetry (CV) and linear sweep voltammetry (LSV). The main decomposition pathway included in the cleavage of chlorine atoms at platinum electrode. The general reduction mechanism of this compound has been suggested based on the results obtained. The peak potential and peak current were found to be depending on pH of the buffer solution. The measuring system response was linear over the vinclozolin concentration range from 1.0×10-3 to 5.0×10-7 mol L-1 and the detection limit (LOD) achieved was 1.1×10-8 mol L-1 (2.5 μg L-1) at pH 4.0. Vinclozolin was determined in spiked serum sample.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (3), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
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15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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