Indexing Metadata
Kinetics and Mechanism of Oxidation of Aniline by
N-Bromophthalimide |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Kinetics and Mechanism of Oxidation of Aniline by
N-Bromophthalimide |
| 2 | Creator | Author's name, affiliation, country | N. M. I. ALHAJI, G. K. AYYADURAI and A. SHAJAHAN
P.G. & Research Department of Chemistry, Khadir Mohideen College, Adirampattinam, Tamilnadu-614701, India
Department of Chemistry, Sri Sai Ram Engineering College, West Tambaram, Chennai, Tamilnadu-600044, India
Department of Chemistry, B. S. AbdurRahman University, Vandalaur, Chennai,
Tamilnadu-600048, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Oxidation, Kinetics, Mechanism, Aniline, N-Bromophthalimide |
| 4 | Description | Abstract | Kinetics of oxidation of aniline by N-bromophthalimide (NBP) in acetonitrile-water solvent mixture at 303 K in the presence of perchloric acid has been followed iodometrically. The reaction is first order with respect to both aniline and NBP and is catalyzed by H+ ion and the order of the reaction with respect to [H+] is also one. It has been found that the reaction rate is not affected by changes in ionic strength of the reaction medium or by the addition of acrylonitrile and potassium bromide. However, addition of phthalimide causes a decrease in the rate of reaction. An increase in the water content of the solvent mixture decreases the rate of reaction. Thermodynamic and activation parameters have also been evaluated. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 2 , Number (2), (2013) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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