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Kinetics and Mechanism of Oxidation of Aniline by
N-Bromophthalimide

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1TitleTitle of DocumentKinetics and Mechanism of Oxidation of Aniline by
N-Bromophthalimide
2CreatorAuthor's name, affiliation, country N. M. I. ALHAJI, G. K. AYYADURAI and A. SHAJAHAN
P.G. & Research Department of Chemistry, Khadir Mohideen College, Adirampattinam, Tamilnadu-614701, India
Department of Chemistry, Sri Sai Ram Engineering College, West Tambaram, Chennai, Tamilnadu-600044, India
Department of Chemistry, B. S. AbdurRahman University, Vandalaur, Chennai,
Tamilnadu-600048, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Oxidation, Kinetics, Mechanism, Aniline, N-Bromophthalimide
4DescriptionAbstract Kinetics of oxidation of aniline by N-bromophthalimide (NBP) in acetonitrile-water solvent mixture at 303 K in the presence of perchloric acid has been followed iodometrically. The reaction is first order with respect to both aniline and NBP and is catalyzed by H+ ion and the order of the reaction with respect to [H+] is also one. It has been found that the reaction rate is not affected by changes in ionic strength of the reaction medium or by the addition of acrylonitrile and potassium bromide. However, addition of phthalimide causes a decrease in the rate of reaction. An increase in the water content of the solvent mixture decreases the rate of reaction. Thermodynamic and activation parameters have also been evaluated.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2013.409
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (2), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
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15CopyrightCopyright and permissions
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