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Metal complexes of N-[Phenyl(pyrrolidin-1-yl) methyl]benzamide: Synthesis, Characterization and Antimicrobial Studies

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1TitleTitle of DocumentMetal complexes of N-[Phenyl(pyrrolidin-1-yl) methyl]benzamide: Synthesis, Characterization and Antimicrobial Studies
2CreatorAuthor's name, affiliation, country L. MURUGANANDAM, K. BALASUBRAMANIAN and K. KRISHNAKUMAR
Department of Chemistry, Saranathan College of Engineering, Tiruchirapalli-620 012, India
Department of Chemistry, National Institute of Technology, Tiruchirapalli-620 015, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Anticonvulsants, Axial perturbation, Multi-component, Pseudo tetrahedral
4DescriptionAbstract A new series of vanadyl(IV), manganese(II), iron(II), nickel(II) and copper(II) complexes of N-[phenyl(pyrrolidin-1-yl)methyl]benzamide(PBB) have been synthesized and characterized by elemental analysis, molar conductance, IR, electronic, EPR spectra and magnetic measurements. Conductance measurements indicate that the above complexes are non-electrolytes. The spectral data show that, the ligand behaves as a neutral bidentate, bonded to metal ions via the carbonyl oxygen of acetamide group and azomethine nitrogen of morpholine moiety. Magnetic susceptibility measurements indicate tetrahedral geometry for NiII chloro, sulphato and CuII nitrato complexes and octahedral geometry for the rest. EPR spectral data suggest ionic link between metal center and the Mannich base ligand. IR studies indicate the presence of water molecules in some of the complexes. The antimicrobial studies show that the CuII complex is more active than others.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2013.412
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (4), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
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