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Synthesis, Characterization of Symmetrically Substituted Metal(II) Octa-1-(3-bromophenyl)methanimine Phthalocyanine |
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1 | Title | Title of Document | Synthesis, Characterization of Symmetrically Substituted Metal(II) Octa-1-(3-bromophenyl)methanimine Phthalocyanine |
2 | Creator | Author's name, affiliation, country | FASIULLA, K. R. VENUGOPALA REDDY*,
J. KESHAVAYYAc and B. CHANDRESHEKHAR KUMARa Department of Chemistry, Manipal Institute of Technology,
Manipal, Udupi District -576104, Karnataka, India
Department of Studies in Industrial Chemistry,
Sahyadri Science College, Shimoga -577201, Shimoga District, Karnataka, India
Department of Studies in Chemistry, Kuvempu University,
Janna Sahyadri, Shankaragatta-577451, Shimoga District, Karnataka, India |
3 | Subject | Dicipline(s) | Chemical Science |
3 | Subject | Keywords | Phthalocyanines, Synthesis, Octa-1-(3-bromophenyl)methanimine, Electronic, Magnetic, XRD, Thermal studies |
4 | Description | Abstract | Metallophthalocyanine (M = Cu, Co, Ni and Zn) carrying eight (3-bromophenyl) methanimine groups at peripheral positions were synthesized by an efficient, simple and novel method. The precursor octaamino metal(II) phthalocyanines were synthesized by the reduction of the corresponding nitro metal phthalocyanines. The dark green octa-1-(3- bromophenyl)methanimine phthalocyanine derivatives were characterized by elemental analysis, magnetic susceptibility, electronic, IR and powder x-ray diffraction studies to check the purity, structural integrity and crystalline properties of the complexes. Magnetic susceptibility studies on Co(II) and Cu(II) octa-1-(3-bromophenyl) methanimine phthalocyanine complexes exhibit a variation of the magnetic moments as a function of field strength indicating the presence of inter molecular co-operative effect. |
5 | Publishers | Organizing agency, location | WWW Publications, India |
6 | Contributor | Sponsor(s) | - |
7 | Date | Date (YYYY-MM-DD) | - |
8 | Type | Status & genre | Peer-reviewed Article |
8 | Type | Type | |
9 | Formate | File Formate | PDF |
10 | Identifier | Uniform Resource Identifier | Click Here |
10 | Identifier | Digital Object Identifier | |
11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 2 , Number (3), (2013) |
12 | Lanuguage | English=en | en |
13 | Relation | Supp.files | |
14 | Coverage | | - |
15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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