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Synthesis, Characterization of Symmetrically Substituted Metal(II) Octa-1-(3-bromophenyl)methanimine Phthalocyanine

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1TitleTitle of DocumentSynthesis, Characterization of Symmetrically Substituted Metal(II) Octa-1-(3-bromophenyl)methanimine Phthalocyanine
2CreatorAuthor's name, affiliation, country FASIULLA, K. R. VENUGOPALA REDDY*, J. KESHAVAYYAc and B. CHANDRESHEKHAR KUMARa
Department of Chemistry, Manipal Institute of Technology, Manipal, Udupi District -576104, Karnataka, India
Department of Studies in Industrial Chemistry, Sahyadri Science College, Shimoga -577201, Shimoga District, Karnataka, India
Department of Studies in Chemistry, Kuvempu University, Janna Sahyadri, Shankaragatta-577451, Shimoga District, Karnataka, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Phthalocyanines, Synthesis, Octa-1-(3-bromophenyl)methanimine, Electronic, Magnetic, XRD, Thermal studies
4DescriptionAbstract Metallophthalocyanine (M = Cu, Co, Ni and Zn) carrying eight (3-bromophenyl) methanimine groups at peripheral positions were synthesized by an efficient, simple and novel method. The precursor octaamino metal(II) phthalocyanines were synthesized by the reduction of the corresponding nitro metal phthalocyanines. The dark green octa-1-(3- bromophenyl)methanimine phthalocyanine derivatives were characterized by elemental analysis, magnetic susceptibility, electronic, IR and powder x-ray diffraction studies to check the purity, structural integrity and crystalline properties of the complexes. Magnetic susceptibility studies on Co(II) and Cu(II) octa-1-(3-bromophenyl) methanimine phthalocyanine complexes exhibit a variation of the magnetic moments as a function of field strength indicating the presence of inter molecular co-operative effect.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (3), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
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