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Structural Aspects and Ion Transport Properties of a New Mixed System BiI3 - Ag2WO4

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1TitleTitle of DocumentStructural Aspects and Ion Transport Properties of a New Mixed System BiI3 - Ag2WO4
2CreatorAuthor's name, affiliation, country V. S. SHANKARAN* and S. AUSTIN SUTHANTHIRARAJ
Department of Energy, University of Madras, Guindy Maraimalai Campus, Chennai 600 025, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Solid electrolyte, FT–IR spectroscopy, DSC, Ion transport number
4DescriptionAbstract An experimental attempt was made to analyze structural and ion transport properties in the case of a new mixed system viz., (BiI3)v - (Ag2WO4)100-v where y = 10, 20, 30, 40, 50, 60, 70, 80 and 90 mol% respectively. The samples synthesized by the rapid melt-quenching technique were analyzed using Fourier Transform Infrared (FT–IR) spectroscopy, differential scanning calorimetric (DSC) analysis and silver ionic transport number studies. The results of FT–IR and DSC studies have revealed the formation of AgI and other phases in various compositions of the system. The transport number measurements carried out by Wagner’s and EMF methods have indicated that silver ions may be responsible for the observed ionic transport in these newly formed solid electrolyte phases.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (3), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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