Indexing Metadata
Direct Electrochemical Synthesis of Aluminium(III)
Thiolates and their Coordination Compounds |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Direct Electrochemical Synthesis of Aluminium(III)
Thiolates and their Coordination Compounds |
| 2 | Creator | Author's name, affiliation, country | BALJIT SINGH, KANCHAN BALA, SUKHVEER SINGH and KISHANPAL SINGH
Department of Chemistry, Punjabi University, Patiala-147002, Punjab, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Electrochemical reactions, Sacrificial electrode, Aluminium(III) thiolates |
| 4 | Description | Abstract | Electrochemical oxidation of a sacrificial aluminum anode with thiols (RSH) like ethanethiol, 2-propanethiol, 1-butanethiol, 2-methyl-2-propanethiol, 1-pentanethiol and thiophenol in the presence of tetrabutylammonium chloride as a conductive additive, acetonitrile as a solvent and platinum as a cathode yield aluminium(III) thiolates. Adducts of these compounds with ligand L (L= 1,10 phenanthroline and
2,2’-bipyridyl) have also been obtained by addition of these ligands to the electrolysis phase. These electrochemically synthesized products have been characterized by microanalysis, physical measurements and IR spectral studies. These have been identified as Al(SR)3 and Al(SR)3.L. All these products are associated with very high current efficiencies. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 2 , Number (4), (2013) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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