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Direct Electrochemical Synthesis of Aluminium(III) Thiolates and their Coordination Compounds

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1TitleTitle of DocumentDirect Electrochemical Synthesis of Aluminium(III) Thiolates and their Coordination Compounds
2CreatorAuthor's name, affiliation, country BALJIT SINGH, KANCHAN BALA, SUKHVEER SINGH and KISHANPAL SINGH
Department of Chemistry, Punjabi University, Patiala-147002, Punjab, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Electrochemical reactions, Sacrificial electrode, Aluminium(III) thiolates
4DescriptionAbstract Electrochemical oxidation of a sacrificial aluminum anode with thiols (RSH) like ethanethiol, 2-propanethiol, 1-butanethiol, 2-methyl-2-propanethiol, 1-pentanethiol and thiophenol in the presence of tetrabutylammonium chloride as a conductive additive, acetonitrile as a solvent and platinum as a cathode yield aluminium(III) thiolates. Adducts of these compounds with ligand L (L= 1,10 phenanthroline and
2,2-bipyridyl) have also been obtained by addition of these ligands to the electrolysis phase. These electrochemically synthesized products have been characterized by microanalysis, physical measurements and IR spectral studies. These have been identified as Al(SR)3 and Al(SR)3.L. All these products are associated with very high current efficiencies.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2013.543
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (4), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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