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Synthesis, Characterization and Ion-Exchange Properties of Terpolymer Resin-II Derived from
p-Hydroxybenzaldehyde, Thiourea and Ethylene Glycol

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1TitleTitle of DocumentSynthesis, Characterization and Ion-Exchange Properties of Terpolymer Resin-II Derived from
p-Hydroxybenzaldehyde, Thiourea and Ethylene Glycol
2CreatorAuthor's name, affiliation, country AMIT N. GUPTA, VINAY V. HIWASE and ASHOK B. KALAMBE
Department of Chemistry, Institute of Science, R. T. Road, Nagpur-440001, India
Arts, Commerce and Science College, Arvi-442201, Dist.-Wardha, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Polycondensation, Ion-exchange, Distribution ratio, Rate of metal ion uptake, Batch-equilibrium method
4DescriptionAbstract Ion-exchange resin (HBTE-II) was synthesized by polycondensation in the presence of polyphosphoric acid as a catalyst using monomers p-hydroxybenzaldehyde (0.2 M), thiourea (0.1 M) and ethylene glycol (0.4 M) at 120 0C. The terpolymer resin was characterized by elemental analysis, the number average molecular weight, UV-Visible, IR and 1H NMR spectrum. Chelating ion-exchange properties of this copolymer were studied for Bi3+, Sb3+, Zn2+ and Mg2+ ions. A batch equilibrium method was employed in the study of the selectivity of metal ion uptake involving the measurements of the distribution of a given metal ion between the polymer sample and a solution containing the metal ion. The study was carried out over a wide pH range and in media of various ionic strengths. The metal ions were estimated spectrophotometrically. The HBTE-II terpolymer resin was found to be selective chelating ion-exchange resin for Sb3+, Bi3+ and Zn2+.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  3 , Number  (1), (2014)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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