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Synthesis, Spectral and Thermal Studies on Schiff Base Derivatives of Heterobimetallic [Ca(II)-Ti(IV)]-μ-oxoisopropoxide

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1TitleTitle of DocumentSynthesis, Spectral and Thermal Studies on Schiff Base Derivatives of Heterobimetallic [Ca(II)-Ti(IV)]-μ-oxoisopropoxide
2CreatorAuthor's name, affiliation, country JAI DEVI and RAJESH KUMAR
Department of Chemistry, Sri Venkateswara University, Gajraula, J.P. Nagar, Uttar Pradesh, India
Department of Chemistry, HCTM Technical Campus, Kaithal-136027, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Heterobimetallic-μ-oxoisopropoxide, Calcium, Titanium, Schiff base, Thermoanalysis
4DescriptionAbstract New Schiff base derivatives of heterobimetallic-μ-oxoisopropoxide [CaO2Ti2(OPri)6] have been synthesized by thermal condensation of μ-oxoisopropoxide with salicylidene-aniline (HSB1), salicylidene-o-toluidene (HSB2) and salicylidene-p-chloroaniline (HSB3) in different molar ratios (1:1-1:4) yielded the compounds of the type [CaO2Ti2(Opri)6-n(SB)n] (where n is 1-4 and SB = Schiff base anion) respectively. The Schiff base derivatives have been characterized by elemental, spectral (IR, 1H, 13C NMR), thermal and molecular weight measurement. Hydrothermally assisted sol-gel process gives the hydrolyzed product and thermal study of these products favors the formation of multicomponent oxides. The studies reveal that Schiff base derivatives are monomeric in nature and low susceptible to hydrolysis as compared to parent compound and may prove excellent precursors for the mixed metal oxides.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2013.595
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  2 , Number  (4), (2013)
12LanuguageEnglish=en en
13RelationSupp.files
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