Indexing Metadata
Synthesis, Spectral and Thermal Studies on
Schiff Base Derivatives of Heterobimetallic
[Ca(II)-Ti(IV)]-μ-oxoisopropoxide |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Synthesis, Spectral and Thermal Studies on
Schiff Base Derivatives of Heterobimetallic
[Ca(II)-Ti(IV)]-μ-oxoisopropoxide |
| 2 | Creator | Author's name, affiliation, country | JAI DEVI and RAJESH KUMAR
Department of Chemistry, Sri Venkateswara University,
Gajraula, J.P. Nagar, Uttar Pradesh, India
Department of Chemistry, HCTM Technical Campus, Kaithal-136027, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Heterobimetallic-μ-oxoisopropoxide, Calcium, Titanium, Schiff base, Thermoanalysis |
| 4 | Description | Abstract | New Schiff base derivatives of heterobimetallic-μ-oxoisopropoxide [CaO2Ti2(OPri)6] have been synthesized by thermal condensation of μ-oxoisopropoxide with salicylidene-aniline (HSB1), salicylidene-o-toluidene (HSB2) and salicylidene-p-chloroaniline (HSB3) in different molar ratios (1:1-1:4) yielded the compounds of the type [CaO2Ti2(Opri)6-n(SB)n] (where n is 1-4 and SB = Schiff base anion) respectively. The Schiff base derivatives have been characterized by elemental, spectral (IR, 1H, 13C NMR), thermal and molecular weight measurement. Hydrothermally assisted sol-gel process gives the hydrolyzed product and thermal study of these products favors the formation of multicomponent oxides. The studies reveal that Schiff base derivatives are monomeric in nature and low susceptible to hydrolysis as compared to parent compound and may prove excellent precursors for the mixed metal oxides. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 2 , Number (4), (2013) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
|
