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Synthesis of Spirocyclopente-Dione Anthracene Adduct, Precursor of the Cyclopentenone Prostagladins
Via Ring-Closing Metathesis Reaction |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Synthesis of Spirocyclopente-Dione Anthracene Adduct, Precursor of the Cyclopentenone Prostagladins
Via Ring-Closing Metathesis Reaction |
| 2 | Creator | Author's name, affiliation, country | GEDSIRIN EKSINITKUN, STEPHEN G. PYNE,
WAYA PHUTDHAWONG and WEERACHAI PHUTDHAWONG
Department of Chemistry, Faculty of Science, Silpakorn University,
Nakhon Pathom-73000, Thailand
School of Chemistry, University of Wollongong, Wollongong, N.S.W-2522, Australia
Department of Chemistry, Faculty of Liberal Arts and Science, Kasetsart University, Kampeang Sean Campus, Nakhon Pathom-73140, Thailand |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Cross-conjugated, Dienone, Ring closing metathesis, Cyclopentenones |
| 4 | Description | Abstract | A synthesis of the spirocyclopente-dione anthracene adduct, a precursor of the cyclopentenone prostaglandins has been reported. The synthesis involved a Diels-Alder reaction of anthracene and dimethyl fumarate to afford 3 followed by reduction, oxidation and esterification reactions to provide methyl ester anthracene adduct 8, which further converted to the the allylic alcohol (12). Then, Ring-Closing Metathesis (RCM) reaction afforded the cyclopentenol anthracene adduct, which after oxidation provided the spirocyclopente-dione anthracene adduct in good yields. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 2 , Number (4), (2013) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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