Indexing Metadata
Synthesis and Spectroscopic Characterization of
Bis and Mono Halide (Antimony(III) O,O’-Ditolyl dithiophosphate) Compounds |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Synthesis and Spectroscopic Characterization of
Bis and Mono Halide (Antimony(III) O,O’-Ditolyl dithiophosphate) Compounds |
| 2 | Creator | Author's name, affiliation, country | SEEMA MAHESHWARI and KRISHAN GOPAL OJHA
Department of Pure & Applied Chemistry, M.D.S. University, Ajmer 305009, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Anisobidentate complexes, Ditolyldithiophosphates, 1H NMR, 31P NMR |
| 4 | Description | Abstract | Antimony complexes of the type [Sb{S2P(OR)2}nCl3-n] (where R = o-, m-, p-C6H4Me; n =1-2) have been obtained by the reaction of antimony(III) chloride with ammonium salts of O,O’-di(o-, m-, p-tolyl) dithiophosphates in 1:2 and 1:1 molar ratio by stirring followed by refluxing in benzene. All these complexes have been characterized by elemental analysis and IR, 1H and 31P NMR spectroscopy. On the basis of experimental and spectroscopic studies distorted trigonal bipyramidal geometry (tbp) around antimony having a lone pair of electron, at axial position may be proposed for the complexes corresponded to [(o-, m- or p-MeC6H4O)2PS 2SbCl2] while an octahedral geometry with a lone pair of electrons may be suggested for the complexes [{(o-,m- or p-MeC6H4O)2PS 2}2SbCl]. |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 3 , Number (2), (2014) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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