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Synthesis, Physiochemical, Thermal, Catalytic and Electrical Studies of Mn(III) VO(IV), MoO2(VI) and UO2 (VI) Complexes with Unsymmetrical Schiff Base Ligand

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1TitleTitle of DocumentSynthesis, Physiochemical, Thermal, Catalytic and Electrical Studies of Mn(III) VO(IV), MoO2(VI) and UO2 (VI) Complexes with Unsymmetrical Schiff Base Ligand
2CreatorAuthor's name, affiliation, country ATISH K. MALDHURE* and ANAND S ASWAR
Department of Chemistry, Sant Gadge Baba Amravati University, Amravati-444602, India
Department of Chemistry, Arts, Commerce and Science College, Narsamma Campus, Kiran Nagar, Amravati-444606, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Unsymmetrical Schiff base, Tetradentate, Electrical conductivity, Catalytic oxidation
4DescriptionAbstract The solid complexes of Mn(III), VO(IV), MoO2(VI) and UO2(VI) with unsymmetrical dibasic tetradentate ONNO donor Schiff base derived from the condensation of salicylaldenyde, o-hydroxy acetophenone and ethylene diamine have been synthesized and characterized by elemental analysis, magnetic susceptibility measurements, IR and reflectance spectra. The thermal dehydration and decomposition of these complexes were studied kinetically using the Horowitz-Metzger method. The solid state electrical conductivity of complexes has been measured in the temperature range 313 K= T =403 K and the complexes exhibited semiconducting behavior. Scanning electron micrograph has also been reported and suggested homogeneous phase material. Complexes were used for the catalytic oxidation of styrene.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  3 , Number  (4), (2014)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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