Indexing Metadata
Synthesis, Structure and Characterization of Adducts of
O-Propyldithiocarbonates with Substituted Pyridines |
| DUBLIN | CORE | METADATA ITEM | METADATA FOR THIS DOCUMENT |
| 1 | Title | Title of Document | Synthesis, Structure and Characterization of Adducts of
O-Propyldithiocarbonates with Substituted Pyridines |
| 2 | Creator | Author's name, affiliation, country | INDERJEET KOUR*, GURPREET KOUR and RENU SACHAR
Department of Chemistry, University of Jammu, Jammu Tawi - 180006, India |
| 3 | Subject | Dicipline(s) | Chemical Science |
| 3 | Subject | Keywords | Adducts, Xanthates (dithiocarbonates), Octahedrally coordinated, Direct methods, Crystal structure, π- π and C-H••• π interaction |
| 4 | Description | Abstract | A series of six coordinated Ni(II)complexes with general formula [Ni(C5H4NCl) 2 (S2COC3H7)2] was synthesized and characterized. All the complexes have 1:2 stoichiometry, are non ionic and paramagnetic in nature. TGA-DTA studies show the formation of NiS as the stable end product of the decomposition. One of the adducts bis(O-propyldithiocarbonato)bis (3-chloropyridine) nickel(II) crystallizes in the monoclinic space group P21/c. The Ni2+ ion is in an octahedral coordination environment formed by an N2S4 donor set, defined by two chelating dithiocarbonate anions as well as two 3-chloropyridine ligands with the Ni2+ ion located at the inversion centre. The packing of layers of molecules is stabilized by weak π - π and C-H•••π interactions. The asymmetric unit comprises of half molecule and Nickel(II) cation lies on an inversion centre |
| 5 | Publishers | Organizing agency, location | WWW Publications, India |
| 6 | Contributor | Sponsor(s) | - |
| 7 | Date | Date (YYYY-MM-DD) | - |
| 8 | Type | Status & genre | Peer-reviewed Article |
| 8 | Type | Type | |
| 9 | Formate | File Formate | PDF |
| 10 | Identifier | Uniform Resource Identifier | Click Here |
| 10 | Identifier | Digital Object Identifier | |
| 11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 3 , Number (3), (2014) |
| 12 | Lanuguage | English=en | en |
| 13 | Relation | Supp.files | |
| 14 | Coverage | | - |
| 15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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