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Synthesis, Characterization and Antifungal Activity of Adducts of Bis(acetylacetonato)oxovanadium(IV) with Heterocyclic Nitrogen Donor Ligands |
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1 | Title | Title of Document | Synthesis, Characterization and Antifungal Activity of Adducts of Bis(acetylacetonato)oxovanadium(IV) with Heterocyclic Nitrogen Donor Ligands |
2 | Creator | Author's name, affiliation, country | RAJINDER SINGH1*, NEERUPAMA, GURPREET KOUR,
POOJA SHARMA and RENU SACHAR Department of Chemistry, University of Jammu, Jammu-180006, India |
3 | Subject | Dicipline(s) | Chemical Science |
3 | Subject | Keywords | Synthesis, Antifungal activity, Heterocyclic nitrogen donor ligand |
4 | Description | Abstract | Monomeric six coordinated adducts of bis(acetylacetonato)oxovanadium(IV) having general formula, [VO(acac)2(L)], [L= pyrrolidine, morpholine, 2,4,6-trimethylpyridine, 2,4, 2,6, 3,4, 3,5-dimethylpyridines, 2-ethylpyridine, 2-methylpyridine, 3-methylpyridine 2, 3, 4-cyanopyridine, quinoline, isoquinoline] have been synthesized and characterized by elemental analysis, IR, electronic spectroscopy, magnetic and conductivity measurements having 1:1 stoichiometry. The adducts were found to be paramagnetic and their magnetic moments at room temperature lie within the 1.72-1.87 B.M. range and this indicates the presence of one unpaired electron. The values are in accordance with the octahedral geometry. The magnetic moment measurements and electronic spectra depicts a octahedral geometry around the vanadium center. The investigated adducts have also tested against the fungus Fusarium oxysporum. |
5 | Publishers | Organizing agency, location | WWW Publications, India |
6 | Contributor | Sponsor(s) | - |
7 | Date | Date (YYYY-MM-DD) | - |
8 | Type | Status & genre | Peer-reviewed Article |
8 | Type | Type | |
9 | Formate | File Formate | PDF |
10 | Identifier | Uniform Resource Identifier | Click Here |
10 | Identifier | Digital Object Identifier | |
11 | Source | Journal/conference title; vol., no. (Year) | Chemical Science Transactions, Volume 3 , Number (3), (2014) |
12 | Lanuguage | English=en | en |
13 | Relation | Supp.files | |
14 | Coverage | | - |
15 | Copyright | Copyright and permissions | |
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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