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Optical Studies in ZnS:Ce Nanocrystallite

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1TitleTitle of DocumentOptical Studies in ZnS:Ce Nanocrystallite
2CreatorAuthor's name, affiliation, country GEORGE VARUGHESE* and K. T. USHA
Department of Physics, Catholicate College, Pathanamthitta, Kerala-689645, India
Department of Chemistry, St. Cyrils College, Adoor, Kerala
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Semiconductor, Nanomaterial, Doping, Ultrasonic velocity
4DescriptionAbstract Cerium doped ZnS nanoparticles were prepared by chemical route. The particle size was determined from the x-ray line broadening. Samples were characterized by XRD, FTIR and UV and SEM. The composition was verified by EDAX spectrum. The size of the particles increased as the annealing temperature was increased. The crystallite size varied from 21.7 nm to 25 nm as the calcination temperature increased. Band gap values Ce3+ doped ZnS were determined to 3.86 eV from the optical transmission studies of the as-prepared samples and exhibited a redshift towards 320 nm in comparison with undoped ZnS nanoparticles. The redshift of the absorption edge to the longer wavelength side has been attributed to the strong exchange interaction between the d electron of Ce and s and p electron of the ZnS host band.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  3 , Number  (4), (2014)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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