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Synthesis and Characterization of Complexes of Rh(II) with Purines and Pyrimidines

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1TitleTitle of DocumentSynthesis and Characterization of Complexes of Rh(II) with Purines and Pyrimidines
2CreatorAuthor's name, affiliation, country R. ILAVARASI1*, L. MUTHULAKSHMI1 and S. SELVANAYAGAM2
1Department of Chemistry, Kalasalingam University, Krishnankoil-626 126, India
2Department Physics, Kalasalingam University, Krishnankoil-626 126, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Metal nucleobase complexes, TG, Electronic, ESCA studies, Theoretical studies
4DescriptionAbstract The reactions of nucleobases and aminoacids with rhodium(II) acetate resulted in the isolation of the complexes of the types Rh2(CH3COO) 4 L(H2O) and Rh2(CH3COO) 4L2. The binding sites of nucleobases towards rhodium(II) and the affinity of heteroatoms in nucleobases towards the metal ion were studied by various characterization techniques. Theoretical calculations have been done on the ligands such as C6H5CH2-ade, hypoxan, Cl-gua, S-gua, cyt and S-url employing modified neglect of differential overlap (MNDO) method to understand their reactivity towards the metal and to compare with the experimental results.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  4 , Number  (1), (2015)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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