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Variation in Electronic Spectral Parameters of Nd(III) and Er(III) with Respect to Ionic Strength of the Medium

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1TitleTitle of DocumentVariation in Electronic Spectral Parameters of Nd(III) and Er(III) with Respect to Ionic Strength of the Medium
2CreatorAuthor's name, affiliation, country SHUBHA MISHRA1, SNEHA WANKAR2, PREETI VISHWAKARMA2, S.K.GHOSH1 and S.N.LIMAYE2
1School of Studies in Physics, Vikram University, Ujjain (M.P.), India
2Department of Chemistry, Dr. H. S. Gour University, A Central University, Sagar (M.P.) 470003, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Judd-Ofelt parameters, Transition probability, Branching ratio, Radiative life time
4DescriptionAbstract The 4f shells are known to have core like structure and were considered as least perturbed by changes around metal ion surroundings, however, there are evidences that the 4f-shells partially involved direct ligand interaction. Keeping in view this observation a systematic studies on the electronic spectral and radiative properties of [Ln(III).L] where L = HEDTA, EDTA and CDTA, in mediums of increasing ionic strengths (μ = 1.0 to 2.5) of NaClO4 have been undertaken with a view to observe the effect of increased compactness of the medium on the electronic spectral parameters of Ln(III) ion. Variations in Oscillator strength, Judd-Ofelt parameter and radiative parameters have been examined as a function of ionic strength of medium, to explore their interdependence.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier DOI:10.7598/cst2015.949
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  4 , Number  (1), (2015)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
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