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Kinetic Study of Co-oxidation of Isopropyl Alcohol with EDTA by Pyridinium Fluorochromate

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1TitleTitle of DocumentKinetic Study of Co-oxidation of Isopropyl Alcohol with EDTA by Pyridinium Fluorochromate
2CreatorAuthor's name, affiliation, country KHUBI LAL REGAR and B. L. HIRAN*
Chemical Kinetics and Polymer Research Laboratory, Department of Chemistry, University College of Science, Mohanlal Sukhadia University, Udaipur 313001, Rajasthan, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Kinetic study, Co-oxidation, Isopropyl alcohol, IPA, Ethylenediaminetetraaceticacids, EDTA, Pyridinium fluorochromate, PFC
4DescriptionAbstract Kinetic study of co-oxidation of isopropyl alcohol (IPA) with ethylenediaminetetraacetic acid (EDTA) by pyridiniumfluorochromate (PFC) has been investigated in the presence of perchloric acid-water medium at 303 °K. The reaction was carried out in induced pseudo first order conditions. The rate of co-oxidation of IPA and EDTA was ten times greater than the combined rate of addition of both compounds separately. EDTA catalyzed the oxidation of IPA. Free radical test proved two electron transfer oxidation and product was Cr(III). Thermodynamic parameters and individual order have been determined. Energy of activation of co-oxidation is 42.52 kcal. mol-1, while individually is 67.55 kcal. mol-1 for IPA & 69.71 kcal. mol-1 for EDTA. Suitable mechanism has been suggested.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  4 , Number  (2), (2015)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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