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Kinetics and Mechanism of Oxidation of some α - Hydroxy Acids by Tripropylammonium Fluorochromate in Aqueous Acetic Acid Medium

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1TitleTitle of DocumentKinetics and Mechanism of Oxidation of some α - Hydroxy Acids by Tripropylammonium Fluorochromate in Aqueous Acetic Acid Medium
2CreatorAuthor's name, affiliation, country S. SHANTHI1 and S. SHEIK MANSOOR2*
1Research and Development Centre, Bharathiar University, Coimbatore-641046, Tamil Nadu, India
2Department of Chemistry, C. Abdul Hakeem College, Melvisharam-632 509, Tamil Nadu, India
3SubjectDicipline(s) Chemical Science
3SubjectKeywords Tripropylammonium fluorochromate, Hydroxy acids, Kinetics, Oxidation
4DescriptionAbstract The oxidation of some α-hydroxy acids like glycolic, lactic and mandelic acids by tripropylammonium fluorochromate (TriPAFC) have been studied in aqueous acetic acid medium. The oxidation leads to the formation of the corresponding oxo acids. The reaction is first order with respect to TriPAFC, hydroxy acids and [H+] and the reaction is catalyzed by hydrogen ions. The reaction has been studied in different percentage of acetic acid-water mixture. A suitable mechanism has been proposed.
5PublishersOrganizing agency, location WWW Publications, India
6Contributor Sponsor(s) -
7DateDate (YYYY-MM-DD) -
8TypeStatus & genre Peer-reviewed Article
8TypeType
9FormateFile Formate PDF
10IdentifierUniform Resource Identifier Click Here
10IdentifierDigital Object Identifier
11SourceJournal/conference title; vol., no. (Year)Chemical Science Transactions, Volume  4 , Number  (1), (2015)
12LanuguageEnglish=en en
13RelationSupp.files
14Coverage -
15CopyrightCopyright and permissions
Chemical Science Transactions | Chem Sci Trans | CST | Online Chemistry Journal | Open Access
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